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Journal/Book: J Magn Reson B
Published: 1996
Pages: 160–180
Volume: 112
Issue:
Accession no.: 25
Publisher:
ISBN:

Directed TOCSY, a method for selection of directed correlations by optimal combinations of isotropic and longitudinal mixing.

S. J. Glaser, H. Schwalbe, J. P. Marino, C. Griesinger
Abstract:
The directed TOCSY pulse sequence element transfers coherence predominantly into "forward-directed" antiphase coherences while simultaneously suppressing in-phase and "backward-directed" antiphase coherences. This novel selection principle, based on the "direction" of the target coherences, provides a new approach for the simplification of crowded spectra. In this article, the theory of directed TOCSY is presented for linear spin systems that are frequently found in carbon-labeled biomolecules.
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Prof. Dr. Harald Schwalbe
Institut für Organische Chemie und Chemische Biologie
Johann Wolfgang Goethe Universität
Max-von-Laue-Str. 7
D-60438 Frankfurt am Main
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